Suggestions by @sotetariah

Frieza

as Jerkass in Sort by Tropes

Huckleberry Finn

as Jerk with a Heart of Gold in Sort by Tropes

Tom Sawyer

as Jerk with a Heart of Gold in Sort by Tropes

Alonzo Harris

as Jerkass in Sort by Tropes

Norman Osborn

as Jerkass in Sort by Tropes

Tuco Salamanca

as Jerkass in Sort by Tropes

Walter White

as Jerkass in Sort by Tropes

Lucius Malfoy

as Jerkass in Sort by Tropes

Spock

as Jerk with a Heart of Gold in Sort by Tropes

Spider-Man (Marvel)

as Jerk-to-Nice-Guy in Sort by Tropes

Peter Parker (Earth-616)

as Jerk-to-Nice-Guy in Sort by Tropes

Peter Parker/Spider-Man (TASM)

as Jerk-to-Nice-Guy in Sort by Tropes

Peter Pan (Hook)

as Jerk-to-Nice-Guy in Sort by Tropes

Sokka

as Jerk-to-Nice-Guy in Sort by Tropes

Ty Lee

as The Nice One in Sort by Tropes

Harry Potter

as The Nice One in Sort by Tropes

Archie Andrews (Archie Comics)

as The Nice One in Sort by Tropes

Spider-Man (Marvel)

as The Nice One in Sort by Tropes

Tony Stark

as Jerk with a Heart of Gold in Sort by Tropes

Ace Ventura

as Jerk with a Heart of Gold in Sort by Tropes