Suggestions by @matthewchadd

Vigo (Ghostbusters)

as Movie Villain in Ranks

Garraka

as Movie Villain in Ranks

Gozer

as Movie Villain in Ranks

Dick Jones (Robocop)

as Movie Villain in Ranks

Lori Quaid

as Movie Villain in Ranks

Vilos Cohaagen (original)

as Movie Villain in Ranks

Lex Luthor (Gene Hackman)

as Movie Villain in Ranks

Medusa (Clash of the Titans)

as Movie Villain in Ranks

Calibos

as Movie Villain in Ranks

Mr. Swackhammer

as Movie Villain in Ranks

Captain Hook (Hook)

as Movie Villain in Ranks

Damon Killian

as Movie Villain in Ranks

Pruneface (Dick Tracy)

as Movie Villain in Ranks

Itchy (Dick Tracy)

as Movie Villain in Ranks

Flattop (Dick Tracy)

as Movie Villain in Ranks

Big Boy Caprice

as Movie Villain in Ranks

Martians (Mars Attacks!)

as Movie Villain in Ranks

Dorian Tyrell

as Movie Villain in Ranks

Grand Admiral Thrawn

as Movie Villain in Ranks

Zira

as Movie Villain in Ranks