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Alfred Stryker is the first villain of Batman, debuting in the same issue as him in Detective Comics #27 in 1939. He was an executive on the Apex Chemical Company and attempted to seize control by murdering his partners.
Alfred Stryker
1939
for 1939 in Fictional Characters Categorized by Year
Suggested by mikeypascual
The movie thing is popular, so I thought I should do one.